Spherical aromaticity of fullerenes.
نویسندگان
چکیده
منابع مشابه
The shielding cone in spherical aromatic structures: insights from models for spherical 2(N + 1)2 aromatic fullerenes.
A direct correlation between π- and spherical aromaticity of the aromatic structures was established by showing that they shared a characteristic shielding cone, resulting from a specific orientation of the applied field. Herein, we revealed the presence of a related long-range shielding cone in spherical aromatic species that was demonstrated through C20, C32, C50, and C60 Hirsh aromatic fulle...
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In this work, two parametric L-Systems have been introduced to generate the figures of two series of nanostructures. These series consist of different spherical fullerenes with various number of carbon atoms. By specifying a parameter in each series a spherical fullerene can be determined. The members of the first series are C60 , C240 , C540 , C940 ,… which can be produced by applying paramete...
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The fullerene-50 is a 'magic number' cage according to the 2(N + 1)(2) rule. For the three lowest isomers of C50 with trigonal and pentagonal symmetries, we calculate the sphericity index, the spherical parentage of the occupied π-orbitals, and the current density in an applied magnetic field. The minimal energy isomer, with D3 symmetry, comes closest to a spherical aromat or a superaromat. In ...
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Aromaticity has been lately in the center of attention of chemists with books [1-3], journal special issues [4-10], reviews [11, 12], and publications (these are too numerous to cite). The discoveries of fullerenes, nanotubes, nanocones, and nanotori as well as the recent techniques for obtaining graphene sheets with monatomic thickness and astounding properties have enlarged our views about th...
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عنوان ژورنال:
- Chemical reviews
دوره 101 5 شماره
صفحات -
تاریخ انتشار 2001